A Meteoric Rise to Excellence!

Episode DP156:

"After Ash has been attacked by Gible for the first time, Brock makes an overt show of his concern on Ash's condition. He was then seen supporting Ash with an arm over Brock's shoulders, once Gible had left." (Bulbapedia, 2012).



You can watch it here, the hottest spots are about 4:40 and 4:59 -
http://watchpokemonepisodes.com/pokemon-episode-618

They couldn't be cuter!

The Scheme Team

Episode AG132 - "Brock's hand is right over Ash's when the group splits into two, and lingers a fraction of a second longer than May and Max's do, despite him not leaving Ash just yet." (Bulbapedia, 2012)

You can watch it here, the scene is about 2:40
http://www.mojvideo.com/video-pokemon-409-the-scheme-team/f2a9b1cdf4fed5dd50d1

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A similar case: Memories are Made of Bliss!
"Near the end of the episode [DP191], before Ash and Brock part ways, they hold hands for a long period of time. They eventually, and slowly, let each other go." (Bulbapedia, 2012)



More screenshots: http://www.filb.de/anime/dp/191


You can watch this episode here
http://watchpokemonepisodes.com/pokemon-episode-653



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